铜催化不对称[2,3]-σ迁移重排实现的高度对映选择性碳-碳键形成：在七元氧杂环和六元碳环合成中的应用
Highly enantioselective carbon-carbon bond formation by Cu-catalyzed asymmetric [2,3]-sigmatropic rearrangement: application to the syntheses of seven-membered oxacycles and six-membered carbocycles.
作者信息
Kumaraswamy Gullapalli, Sadaiah Kadivendi, Ramakrishna Duggirala Subrahmanya, Police Naresh, Sridhar Balasubramanian, Bharatam Jagadeesh
机构信息
Organic Division-III, Indian Institute of Chemical Technology, Hyderabad, India.
出版信息
Chem Commun (Camb). 2008 Nov 14(42):5324-6. doi: 10.1039/b810770j. Epub 2008 Sep 17.
DOI:10.1039/b810770j
PMID:18985198
Abstract
A concise route for the syntheses of enantioenriched functionalized scaffolds of medium-sized oxacycles and carbocycles employing the chiral auxiliary-mediated Cu-catalyzed ylide formation/[2,3]-sigmatropic rearrangement as a key step was developed.
摘要
开发了一种简洁的合成路线，以手性辅助介导的铜催化叶立德形成/[2,3] - 西格玛重排为关键步骤，合成对映体富集的中等大小含氧杂环和碳环的功能化骨架。
Zotero 插件