银（I）催化的炔丙醇和氮杂环丙烷/氮杂环丁烷的双重活化：级联反应中引发开环和内选择性闭环。
Silver(I)-catalyzed dual activation of propargylic alcohol and aziridine/azetidine: triggering ring-opening and endo-selective ring-closing in a cascade.
机构信息
Organometallics & Catalysis Laboratory, Chemistry Department, Indian Institute of Technology, Kharagpur 721302, India.
出版信息
J Org Chem. 2009 Nov 20;74(22):8814-7. doi: 10.1021/jo901877f.
PMID:19831345
Abstract
[Ag(COD)(2)]PF(6) catalyzes the reaction between propargyl alcohols and N-tosylaziridines/azetidines leading to a diverse range of N,O-heterocycles, namely, oxazines, oxazepines, and oxazocines via ring-opening and ring-closing in a cascade.
摘要
[Ag(COD)(2)]PF(6) 催化炔丙醇与 N-对甲苯磺酰基氮杂环丙烷/氮杂环丁烷的反应，通过级联的开环和闭环反应生成各种 N,O-杂环化合物，即恶嗪、恶唑嗪和恶唑烷。
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