Zhang Jie-Peng, Huang Xiao-Chun, Chen Xiao-Ming
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Chem Soc Rev. 2009 Aug;38(8):2385-96. doi: 10.1039/b900317g. Epub 2009 May 19.
Coordination polymers have been emerging as a topical research field in crystal engineering, solid-state chemistry, and materials science. Considering the wide occurrence of structural and compositional diversity during self-assembly and crystallization, supramolecular isomerism represents an indication of composition control and structure prediction. Actually, supramolecular isomerism is not just an obstacle or challenge, but also a good opportunity for developing novel materials and a better understanding of self-assembly and crystal growth. This critical review provides an overview of the developing knowledge, in the context of supramolecular isomerism, of the design, synthesis, and properties of coordination polymers (97 references).
配位聚合物已成为晶体工程、固态化学和材料科学领域的一个热门研究方向。鉴于在自组装和结晶过程中结构和组成多样性的广泛存在，超分子异构现象是组成控制和结构预测的一个指标。实际上，超分子异构现象不仅是一个障碍或挑战，也是开发新型材料以及更好地理解自组装和晶体生长的一个良好机遇。本综述文章概述了在超分子异构现象背景下，配位聚合物的设计、合成及性质方面的发展知识（参考文献97篇）。
