Heterocyclization by catalytic carbonickelation of alkynes: a domino sequence involving vinylnickels.
作者信息
Durandetti Muriel, Hardou Lucie, Clément Marie, Maddaluno Jacques
机构信息
Laboratoire des Fonctions Azotées & Oxygénées Complexes de l'IRCOF, CNRS UMR 6014 & FR 3038, Université de Rouen et INSA de Rouen, 76821 Mont St Aignan Cedex, France.
出版信息
Chem Commun (Camb). 2009 Aug 21(31):4753-5. doi: 10.1039/b902095k. Epub 2009 Jul 6.
DOI:10.1039/b902095k
PMID:19641832
Abstract
Reaction of Ni(0) in the presence of iodoarylethers leads, after syn intramolecular carbonickelation of the triple bond, to nucleophilic vinylnickels which can be trapped, in a tandem process, by various electrophiles introduced at the onset of the reaction.
摘要
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