饱和C-H键胺化反应中的关键中间体：Ru(TPP)(NAr)₂（Ar = 3,5-(CF₃)₂C₆H₃）的合成、X射线表征及催化活性
The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3)).
作者信息
Fantauzzi Simone, Gallo Emma, Caselli Alessandro, Ragaini Fabio, Casati Nicola, Macchi Piero, Cenini Sergio
机构信息
Dipartimento di Chimica Inorganica, Metallorganica e Analitica L Malatesta, Università di Milano and ISTM-CNR, Milano, Italy.
出版信息
Chem Commun (Camb). 2009 Jul 14(26):3952-4. doi: 10.1039/b903238j. Epub 2009 May 29.
DOI:10.1039/b903238j
PMID:19662263
Abstract
The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.
摘要
配合物Ru(TPP)(NAr)₂将氮烯基团插入烯丙基和苄基的C-H键中，并且是钌卟啉催化芳基叠氮化物对烃进行胺化反应中的关键中间体。
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