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通过纳米孔的强迫聚合物转位的标度指数。

Scaling exponents of forced polymer translocation through a nanopore.

作者信息

Bhattacharya A, Morrison W H, Luo K, Ala-Nissila T, Ying S-C, Milchev A, Binder K

机构信息

Department of Physics, University of Central Florida, Orlando, FL 32816-2385, USA.

出版信息

Eur Phys J E Soft Matter. 2009 Aug;29(4):423-9. doi: 10.1140/epje/i2009-10495-5. Epub 2009 Aug 8.

DOI:10.1140/epje/i2009-10495-5
PMID:19669181
Abstract

We investigate several properties of a translocating homopolymer through a thin pore driven by an external field present inside the pore only using Langevin Dynamics (LD) simulations in three dimensions (3D). Motivated by several recent theoretical and numerical studies that are apparently at odds with each other, we estimate the exponents describing the scaling with chain length (N) of the average translocation time , the average velocity of the center of mass , and the effective radius of gyration during the translocation process defined as approximately Nalpha, approximately N(-delta), and Rg approximately Nnu respectively, and the exponent of the translocation coordinate (s-coordinate) as a function of the translocation time <s2(t)> approximately tbeta. We find alpha = 1.36 +/- 0.01, beta = 1.60+/- 0.01 for <s2(t)> approximately taubeta and beta = 1.44 +/- 0.02 for <Deltas2(t)> approximately taubeta, delta = 0.81 +/- 0.04, and nu congruent with nu = 0.59 +/- 0.01, where nu is the equilibrium Flory exponent in 3D. Therefore, we find that approximately N1.36 is consistent with the estimate of approximately /. However, as observed previously in Monte Carlo (MC) calculations by Kantor and Kardar (Y. Kantor, M. Kardar, Phys. Rev. E 69, 021806 (2004)) we also find the exponent alpha = 1.36 +/- 0.01 < 1 + nu. Further, we find that the parallel and perpendicular components of the gyration radii, where one considers the "cis" and "trans" parts of the chain separately, exhibit distinct out-of-equilibrium effects. We also discuss the dependence of the effective exponents on the pore geometry for the range of N studied here.

摘要

我们仅使用三维(3D)的朗之万动力学(LD)模拟,研究了在仅存在于孔内部的外场驱动下,穿过细孔的易位均聚物的几个性质。受近期一些明显相互矛盾的理论和数值研究的启发,我们估计了描述易位过程中平均易位时间〈τ〉、质心平均速度〈vCM〉和有效回转半径〈Rg〉随链长(N)缩放的指数,分别定义为〈τ〉≈Nα、〈vCM〉≈N-δ和〈Rg〉≈Nν,以及作为易位时间函数的易位坐标(s坐标)的指数〈s2(t)〉≈tβ。我们发现,对于〈s2(t)〉≈tβ,α = 1.36±0.01,β = 1.60±0.01;对于〈Δs2(t)〉≈tβ,β = 1.44±0.02,δ = 0.81±0.04,且ν≈0.59±0.01,其中ν是3D中的平衡弗洛里指数。因此,我们发现〈τ〉≈N1.36与〈τ〉≈〈Rg〉/〈vCM〉的估计一致。然而,正如之前在Kantor和Kardar的蒙特卡罗(MC)计算中所观察到的(Y. Kantor, M. Kardar, Phys. Rev. E 69, 021806 (2004)),我们还发现指数α = 1.36±0.01 < 1 + ν。此外,我们发现回转半径的平行和垂直分量,其中分别考虑链的“顺式”和“反式”部分,表现出明显的非平衡效应。我们还讨论了在此研究的N范围内有效指数对孔几何形状的依赖性。

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本文引用的文献

1
Comment on 'Anomalous dynamics of unbiased polymer translocation through a narrow pore' and other recent papers by D Panja, G Barkema and R Ball.对D·潘贾、G·巴克马和R·鲍尔所著的《无偏聚合物通过窄孔的反常动力学》及其他近期论文的评论
J Phys Condens Matter. 2009 Mar 4;21(9):098001. doi: 10.1088/0953-8984/21/9/098001. Epub 2009 Jan 30.
2
Nondriven polymer translocation through a nanopore: computational evidence that the escape and relaxation processes are coupled.非驱动聚合物通过纳米孔的转运:逃逸与弛豫过程耦合的计算证据。
Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Feb;79(2 Pt 1):021802. doi: 10.1103/PhysRevE.79.021802. Epub 2009 Feb 11.
3
带电聚合物在单价和二价盐溶液中通过纳米孔的转位:一项探索整个驱动力范围的标度研究
Polymers (Basel). 2018 Nov 6;10(11):1229. doi: 10.3390/polym10111229.
4
Theoretical Modeling of Polymer Translocation: From the Electrohydrodynamics of Short Polymers to the Fluctuating Long Polymers.聚合物转位的理论建模:从短聚合物的电流体动力学到波动的长聚合物
Polymers (Basel). 2019 Jan 11;11(1):118. doi: 10.3390/polym11010118.
5
Driven translocation of a semi-flexible polymer through a nanopore.半柔性聚合物通过纳米孔的驱动转运。
Sci Rep. 2017 Aug 7;7(1):7423. doi: 10.1038/s41598-017-07227-3.
6
Smooth DNA transport through a narrowed pore geometry.通过变窄的孔道几何结构实现DNA的顺畅运输。
Biophys J. 2014 Nov 18;107(10):2381-93. doi: 10.1016/j.bpj.2014.10.017.
7
Conformation-dependent translocation of a star polymer through a nanochannel.星型聚合物通过纳米通道的构象依赖性转位
Biomicrofluidics. 2014 Sep 10;8(5):054107. doi: 10.1063/1.4893637. eCollection 2014 Sep.
8
Translocation of polymers in a lattice model.
Eur Phys J E Soft Matter. 2012 Jun;35(6):47. doi: 10.1140/epje/i2012-12047-4. Epub 2012 Jun 15.
Dynamical scaling exponents for polymer translocation through a nanopore.
Phys Rev E Stat Nonlin Soft Matter Phys. 2008 Nov;78(5 Pt 1):050901. doi: 10.1103/PhysRevE.78.050901. Epub 2008 Nov 3.
4
Probability distributions for polymer translocation.
Phys Rev E Stat Nonlin Soft Matter Phys. 2008 Aug;78(2 Pt 1):021129. doi: 10.1103/PhysRevE.78.021129. Epub 2008 Aug 21.
5
A Monte Carlo algorithm to study polymer translocation through nanopores. I. Theory and numerical approach.一种用于研究聚合物通过纳米孔转位的蒙特卡罗算法。I. 理论与数值方法。
J Chem Phys. 2008 Feb 14;128(6):065103. doi: 10.1063/1.2826339.
6
Molecular Dynamics simulation of a polymer chain translocating through a nanoscopic pore: hydrodynamic interactions versus pore radius.聚合物链通过纳米孔的分子动力学模拟:流体动力学相互作用与孔径的关系
Eur Phys J E Soft Matter. 2008 Jan;25(1):17-23. doi: 10.1140/epje/i2007-10257-5. Epub 2008 Jan 31.
7
Nonequilibrium dynamics of polymer translocation and straightening.聚合物转位与伸直的非平衡动力学。
Phys Rev E Stat Nonlin Soft Matter Phys. 2007 Aug;76(2 Pt 1):021803. doi: 10.1103/PhysRevE.76.021803. Epub 2007 Aug 29.
8
Polymer translocation through a nanopore: a showcase of anomalous diffusion.
Phys Rev E Stat Nonlin Soft Matter Phys. 2007 Jul;76(1 Pt 1):010801. doi: 10.1103/PhysRevE.76.010801. Epub 2007 Jul 13.
9
Unforced translocation of a polymer chain through a nanopore: the solvent effect.聚合物链通过纳米孔的非强制转运:溶剂效应。
J Chem Phys. 2007 May 28;126(20):204901. doi: 10.1063/1.2735627.
10
Heteropolymer translocation through nanopores.杂聚物通过纳米孔的转运
J Chem Phys. 2007 Apr 14;126(14):145101. doi: 10.1063/1.2719198.