在溶剂热条件下，通过在CHCl₃上进行双C-C偶联原位形成新配体来组装一维配位聚合物。

Assembly of a 1D coordination polymer through in situ formation of a new ligand by double C-C coupling on CHCl3 under solvothermal conditions.

作者信息

Li Guo-Bi, Liu Jun-Min, Yu Zhi-Quan, Wang Wei, Su Cheng-Yong

机构信息

MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

出版信息

Inorg Chem. 2009 Sep 21;48(18):8659-61. doi: 10.1021/ic9011263.

DOI:10.1021/ic9011263

PMID:19689104

Abstract

A rare in situ metal/ligand reaction has been observed during the assembly of a manganese-coordination polymer under solvothermal conditions, which leads to double C-C coupling on CHCl(3) involving cleavage of three C-Cl bonds and the formation of two new C-C bonds at the same carbon center.

摘要

在溶剂热条件下组装锰配位聚合物的过程中，观察到一种罕见的原位金属/配体反应，该反应导致CHCl₃上发生双C-C偶联，涉及三个C-Cl键的断裂，并在同一碳中心形成两个新的C-C键。