钯催化[60]富勒烯与酰苯胺通过C-H键活化的杂环化反应。
Palladium-catalyzed heteroannulation of [60]fullerene with anilides via C-H bond activation.
作者信息
Zhu Bo, Wang Guan-Wu
机构信息
Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China.
出版信息
Org Lett. 2009 Oct 1;11(19):4334-7. doi: 10.1021/ol901675t.
PMID:19731923
Abstract
The palladium-catalyzed reaction of [60]fullerene with a variety of readily available anilides, initiated by C-H bond activation and followed by cyclization, afforded [60]fulleroindolines in a highly regioselective manner. A plausible reaction mechanism was proposed.
摘要
钯催化的[60]富勒烯与各种易得的酰苯胺反应，由C-H键活化引发，随后环化，以高度区域选择性的方式得到[60]富勒吲哚啉。提出了一种合理的反应机理。
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