Department of Organic Chemistry, University of Bucharest, Bulevardul Regina Elisabeta 4-12, RO-030018 Bucharest-1, Romania.
Magn Reson Chem. 2009 Dec;47(12):1031-5. doi: 10.1002/mrc.2507.
The 1H and 13C NMR chemical shifts of 1,2,3,4,5,6,7,8-octahydroacridine, 12 of its 9-substituted derivatives, and of the corresponding N-oxides were determined, assigned, and discussed in terms of 9-substituent effects and effects of N-oxidation. A good linear correlation was found between the 13C chemical shifts of the aromatic carbons in octahydroacridines and those of respective carbons in the corresponding N-oxides.
1,2,3,4,5,6,7,8-八氢吖啶、其 9 位取代衍生物和相应的 N-氧化物的 1H 和 13C NMR 化学位移已被测定、归属,并根据 9 位取代基效应和 N-氧化效应进行了讨论。在八氢吖啶的芳碳的 13C 化学位移和相应的 N-氧化物的各碳的 13C 化学位移之间发现了良好的线性相关性。