Furukawa Shunsuke, Kobayashi Junji, Kawashima Takayuki
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-0033 Tokyo, Japan.
J Am Chem Soc. 2009 Oct 14;131(40):14192-3. doi: 10.1021/ja906566r.
An intramolecular sila-Friedel-Crafts reaction was developed and applied to the synthesis of dibenzosilole derivatives. This reaction proceeds under mild conditions to afford the target in relatively high yield, indicating its availability as a versatile synthetic method. The synthesis of trisilasumanene, a silicon analogue of sumanene, was achieved using the present reaction.
开发了一种分子内硅-傅克反应并将其应用于二苯并硅杂环戊二烯衍生物的合成。该反应在温和条件下进行，以相对较高的产率得到目标产物，表明其作为一种通用合成方法的实用性。使用本反应实现了六硅代苏曼烯（苏曼烯的硅类似物）的合成。
