Department of Chemistry, Shantou University, Guangdong 515063, PR China.
Chem Commun (Camb). 2009 Dec 7(45):6943-5. doi: 10.1039/b911955h. Epub 2009 Oct 19.
The reversible crystal transformation between a hexagonal (R3[combining macron]) porous coordination architecture Cu(L)(2) (L = 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole), and a monoclinic (C2/c) molecular tecton [Cu(L)(2)(H(2)O)], was chemically implemented and structurally interpreted.
六方(R3[combining macron])多孔配位结构[Cu(L)(2)](n)(L=3-(吡啶-4-基)-5-(吡嗪-2-基)-1H-1,2,4-三唑)与单斜(C2/c)分子构象[Cu(L)(2)(H(2)O)]之间的可逆晶体转变,通过化学方法实现并进行了结构解释。