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二水合双-[5-(吡嗪-2-基)-3-(吡啶-4-基)-1H-1,2,4-三唑-1-基-κN]锌

Diaqua-bis-[5-(pyrazin-2-yl)-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN]zinc.

作者信息

Li Bo, Liu Peng-Wen, Chen Jing

机构信息

College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m203. doi: 10.1107/S1600536812002061. Epub 2012 Jan 25.

Abstract

The title mononuclear complex, [Zn(C(11)H(7)N(6))(2)(H(2)O)(2)], is composed of one Zn(II) ion, two deprotonated ppt ligands [Hppt = 5-(pyrazin-2-yl)-3-(pyridin-4-yl)-1H-1,2,4-triazole] and two coordinating water mol-ecules. The asymmetric unit consists of one half-mol-ecule that is completed by application of a centre of symmetry. The Zn(II) atom is six-coordinated in an octa-hedral environment, surrounded by two O atoms in the axial positions and four N atoms in the equatorial plane. Adjacent mononuclear units are further linked via O-H⋯N hydrogen-bonding inter-actions, forming a two-dimensional network along (100).

摘要

标题单核配合物[Zn(C₁₁H₇N₆)₂(H₂O)₂]由一个Zn(II)离子、两个去质子化的ppt配体[Hppt = 5-(吡嗪-2-基)-3-(吡啶-4-基)-1H-1,2,4-三唑]和两个配位水分子组成。不对称单元由通过对称中心作用完成的半个分子组成。Zn(II)原子在八面体环境中呈六配位,轴向位置有两个O原子,赤道平面有四个N原子。相邻的单核单元通过O-H⋯N氢键相互作用进一步连接,沿(100)形成二维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae97/3274922/80535b100b13/e-68-0m203-fig1.jpg

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