Ronsin O, Caroli C, Baumberger T
INSP, UPMC Université Paris 06, CNRS UMR 7588, 75015 Paris, France.
Phys Rev Lett. 2009 Sep 25;103(13):138302. doi: 10.1103/PhysRevLett.103.138302. Epub 2009 Sep 22.
We show that the aging of the mechanical relaxation of a gelatin gel exhibits the same scaling phenomenology as polymer and colloidal glasses. In addition, gelatin is known to exhibit logarithmic structural aging (stiffening). We find that stress accelerates this process. However, this effect is definitely irreducible to a mere age shift with respect to natural aging. We suggest that it is interpretable in terms of elastically aided elementary (coil --> helix) local events whose dynamics gradually slows down as aging increases geometric frustration.
我们表明,明胶凝胶的机械弛豫老化表现出与聚合物和胶体玻璃相同的标度现象学。此外,已知明胶会表现出对数结构老化(硬化)。我们发现应力会加速这一过程。然而,这种效应绝对不能简单地归结为相对于自然老化的年龄偏移。我们认为,这可以用弹性辅助的基本(卷曲→螺旋)局部事件来解释,随着老化增加几何挫折感,其动力学逐渐减慢。