醛与末端炔烃通过钌催化脱羰加成的烯烃化反应。
An olefination via ruthenium-catalyzed decarbonylative addition of aldehydes to terminal alkynes.
机构信息
Department of Chemistry, McGill University, Montreal, QC, Canada H3A 2K6.
出版信息
J Am Chem Soc. 2009 Oct 28;131(42):15092-3. doi: 10.1021/ja906265a.
PMID:19919154
Abstract
A ruthenium-catalyzed olefination via decarbonylative addition of aldehydes and alkynes has been developed. A strong electronic effect and high chemoselectivity between aromatic and aliphatic aldehydes were observed in this reaction.
摘要
发展了一种通过醛和炔烃的脱羰加成反应的钌催化烯烃化反应。在该反应中观察到芳香醛和脂肪醛之间具有强烈的电子效应和高化学选择性。
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