金属有机框架的共价表面修饰：通过铜（I）催化的惠斯根环加成反应进行选择性表面工程
Covalent surface modification of a metal-organic framework: selective surface engineering via Cu(I)-catalyzed Huisgen cycloaddition.
作者信息
Gadzikwa Tendai, Lu Guang, Stern Charlotte L, Wilson Scott R, Hupp Joseph T, Nguyen Sonbinh T
机构信息
Department of Chemistry, Northwestern University, Evanston, IL 60208-3113, USA.
出版信息
Chem Commun (Camb). 2008 Nov 21(43):5493-5. doi: 10.1039/b805101a. Epub 2008 Oct 8.
DOI:10.1039/b805101a
PMID:18997929
Abstract
A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via'click chemistry', in a demonstration of selective post-synthesis functionalization.
摘要
一种带有三甲基硅基保护乙炔的锌角混合配体金属有机框架（MOF）已被构建，并且通过“点击化学”用有机分子对其表面进行了修饰，这展示了选择性的合成后功能化。
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