Xia Yuzheng, Liu Hui, Shi Shuxian, Chen Xiaonong, Jiao Shuke
The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Material Science and Engineering College, Beijing University of Chemical Technology, Beijing 100029, China.
Sheng Wu Yi Xue Gong Cheng Xue Za Zhi. 2009 Oct;26(5):1047-51.
Poly (acrylic ester) hydrogel materials were widely used in intraocular lens and contact lens because of their excellent optical performance and biocompatibility. In this paper, the bulk copolymerization behavior of hydrophilic hydroxyethyl methacrylat with hydrophobic methyl metharylate was studied; and the optical performance, calcium deposits, equilibrium water content of polymers and its hydrogels obtained by different ratios of monomers were systematically investigated. The experimental results showed that the average light transmittance and the equilibrium water content of the obtained hydrogels increased with the increasing of the hydrophilic monomer content from 0 to 100%; however, the hardness decreased. The highest light transmittance reached 97% and the hardness of Shore A fell from 92 to 25, the equilibrium water content of hydrogel increased from 16% to 64%. The absorbent capacity of copolymers reduced with the adding of cross-linking monomer. When m(hydrophilic monomer): m(hydrophobic monomer) = 90 : 10, the combination property of the polymer and its hydrogel obtained is optimum.
聚(丙烯酸酯)水凝胶材料因其优异的光学性能和生物相容性而被广泛应用于人工晶状体和隐形眼镜。本文研究了亲水性甲基丙烯酸羟乙酯与疏水性甲基丙烯酸甲酯的本体共聚行为;并系统研究了不同单体比例得到的聚合物及其水凝胶的光学性能、钙沉积、平衡含水量。实验结果表明,随着亲水性单体含量从0增加到100%,所得水凝胶的平均透光率和平衡含水量增加;然而,硬度降低。最高透光率达到97%,邵氏A硬度从92降至25,水凝胶的平衡含水量从16%增加到64%。共聚物的吸水能力随着交联单体的加入而降低。当亲水性单体与疏水性单体的质量比为90:10时,所得聚合物及其水凝胶的综合性能最佳。