2D 超快 HMBC：监测有机反应的有力工具。

2D ultrafast HMBC: a valuable tool for monitoring organic reactions.

机构信息

Departamento de Química Orgánica and CAI de RMN Facultad de Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain.

出版信息

Org Lett. 2010 Jan 1;12(1):144-7. doi: 10.1021/ol902532f.

DOI:10.1021/ol902532f

PMID:19947620

Abstract

Ultrafast 2D HMBC spectroscopy permits real-time monitoring of a reaction based on the structural changes produced in a carbonyl carbon atom. This new technique was used to study the reaction of ketones, nitriles, and Tf(2)O, affording relevant information about new intermediates and kinetic data.

摘要

超快二维 HMBC 光谱学允许基于羰基碳原子产生的结构变化实时监测反应。这项新技术用于研究酮、腈和 Tf(2)O 的反应，提供有关新中间体和动力学数据的相关信息。