Key Laboratory on Luminescence and Real-Time Analysis, Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University, Beibei, Chongqing 400715, PR China.
Spectrochim Acta A Mol Biomol Spectrosc. 2010 Feb;75(2):553-7. doi: 10.1016/j.saa.2009.11.015. Epub 2009 Nov 13.
Herein, we prepared water-soluble fluorescent carbon dots with diameter about 1.5 nm from cheap commercial lampblack. These fluorescent carbon nanoparticles are stable toward photobleaching and stable in water for more than half a year without fluorescence decrease. In order to improve its fluorescence properties, we passivated these nanoparticles with bisamino-terminated polyethylene glycol (PEG(1500 N)). Therefore, both fluorescence quantum yield and lifetime increased after this progress. In addition, the passivated carbon dots were more inert to solvent than the bare one and showed different responses to pH change.
在此,我们使用廉价的商用油烟制备了直径约 1.5nm 的水溶性荧光碳点。这些荧光碳纳米粒子对光漂白稳定,在水中稳定半年以上而荧光强度没有下降。为了提高其荧光性能,我们用双氨基封端的聚乙二醇(PEG(1500N))对这些纳米粒子进行了钝化。因此,经过这一过程后,荧光量子产率和寿命都提高了。此外,与未钝化的碳点相比,钝化后的碳点对溶剂的惰性更强,对 pH 值变化的响应也不同。