Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong, China.
Chem Commun (Camb). 2010 Jan 14;46(2):213-5. doi: 10.1039/b914516h. Epub 2009 Sep 16.
Silver(I) salts mediated stereospecific transformation of optically active propargylamines to axially chiral allenes with excellent enantioselectivities (17 examples with 96-99% ee; one substrate with 91% ee) without subsequent racemization.
银（I）盐介导的旋光活性炔丙胺立体特异性转化为轴手性烯丙基，具有极好的对映选择性（17 个实例，ee 值为 96-99%；一个实例，ee 值为 91%），且没有随后的外消旋化。
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