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低估了北欧木材行业萜烯暴露的风险。

Underestimation of terpene exposure in the Nordic wood industry.

机构信息

Department of Energy, Environmental and Building Technology, Karlstad University, Karlstad, Sweden.

出版信息

J Occup Environ Hyg. 2010 Mar;7(3):144-51. doi: 10.1080/15459620903476330.

Abstract

This study determined that emission of sesquiterpenes from processed wood warrants attention in the work environment. Currently, only the monoterpenes in the terpene group are monitored in occupational hygiene studies. Terpene emissions are a work environment issue for industries that process wood, as they are known to cause respiratory difficulties and mucous membrane irritation. Fresh sawdust of the most common boreal conifers, Norway spruce (Picea abies) and Scots pine (Pinus sylvestris), was subjected to processing (drying), and the emissions were analyzed with a gas chromatograph-mass spectrometer. The data indicate that workers are exposed to significant amounts of sesquiterpenes, an observation that has not been recorded previously at wood processing plants. On average, the proportion of sesquiterpenes to monoterpenes was 21 +/- 5% (STD, n = 11) for spruce and 15 +/- 5% (STD, n = 13) for pine. The composition of terpenes emitted in air from spruce wood differs from the composition in resin. The sum of monoterpenes and sesquiterpenes can exceed the occupational exposure limit for turpentine for processes where monoterpene concentrations are already close to the occupational exposure limit, and for processes involving the processing of bark. Findings suggest that future studies of health effects from terpenes in air should measure monoterpenes and sesquiterpenes to assess whether the current OELs are appropriate.

摘要

本研究确定了加工木材释放的倍半萜烯值得在工作环境中引起关注。目前,职业卫生研究中仅监测萜烯类中的单萜烯。萜烯类排放是加工木材的行业的工作环境问题,因为它们已知会引起呼吸道困难和粘膜刺激。最常见的北方针叶树挪威云杉(Picea abies)和欧洲赤松(Pinus sylvestris)的新鲜锯末被加工(干燥),并用气相色谱-质谱仪对排放物进行了分析。数据表明,工人暴露于大量的倍半萜烯中,这一观察结果以前在木材加工厂中并未记录到。平均而言,云杉的倍半萜烯与单萜烯的比例为 21 +/- 5%(标准偏差,n = 11),而松树为 15 +/- 5%(标准偏差,n = 13)。从云杉木材空气中排放的萜烯的组成与树脂中的组成不同。单萜烯和倍半萜烯的总和可能超过松节油的职业暴露限值,对于单萜烯浓度已经接近职业暴露限值的工艺,以及涉及树皮加工的工艺,情况更是如此。研究结果表明,未来空气中萜烯对健康影响的研究应测量单萜烯和倍半萜烯,以评估当前的 OEL 是否合适。

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