National Centre for Nanoscience and Technology, Beijing, 100190, China.
J Am Chem Soc. 2010 Jan 27;132(3):944-6. doi: 10.1021/ja909228n.
We report that gold thermally deposited onto n-layer graphenes interacts differently with these substrates depending on the number layer, indicating the different surface properties of graphenes. This results in thickness-dependent morphologies of gold on n-layer graphenes, which can be used to identify and distinguish graphenes with high throughput and spatial resolution. This technique may play an important role in checking if n-layer graphenes are mixed with different layer numbers of graphene with a smaller size, which cannot be found by Raman spectra. The possible mechanisms for these observations are discussed.
我们报告称,沉积在 n 层石墨烯上的金与这些基底的相互作用因层数而异,这表明了石墨烯具有不同的表面性质。这导致了金在 n 层石墨烯上的厚度依赖性形态,这可以用于以高通量和高空间分辨率来识别和区分石墨烯。这项技术可能在检查 n 层石墨烯是否与较小尺寸的不同层数的石墨烯混合方面发挥重要作用,而拉曼光谱无法发现这些石墨烯。我们讨论了这些观察结果的可能机制。