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P25-石墨烯复合材料作为一种高性能光催化剂。

P25-graphene composite as a high performance photocatalyst.

机构信息

Department of Chemistry, Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology, Tsinghua University, Beijing 100084, China.

出版信息

ACS Nano. 2010 Jan 26;4(1):380-6. doi: 10.1021/nn901221k.

Abstract

Herein we obtained a chemically bonded TiO(2) (P25)-graphene nanocomposite photocatalyst with graphene oxide and P25, using a facile one-step hydrothermal method. During the hydrothermal reaction, both of the reduction of graphene oxide and loading of P25 were achieved. The as-prepared P25-graphene photocatalyst possessed great adsorptivity of dyes, extended light absorption range, and efficient charge separation properties simultaneously, which was rarely reported in other TiO(2)-carbon photocatalysts. Hence, in the photodegradation of methylene blue, a significant enhancement in the reaction rate was observed with P25-graphene, compared to the bare P25 and P25-CNTs with the same carbon content. Overall, this work could provide new insights into the fabrication of a TiO(2)-carbon composite as high performance photocatalysts and facilitate their application in the environmental protection issues.

摘要

在此,我们使用简便的一步水热法获得了一种化学结合的 TiO(2)(P25)-石墨烯纳米复合材料光催化剂,其中包含氧化石墨烯和 P25。在水热反应过程中,同时实现了氧化石墨烯的还原和 P25 的负载。所制备的 P25-石墨烯光催化剂同时具有优异的染料吸附能力、扩展的光吸收范围和高效的电荷分离性能,这在其他 TiO(2)-碳光催化剂中很少报道。因此,在亚甲基蓝的光降解反应中,与具有相同碳含量的 P25-CNTs 相比,P25-石墨烯表现出显著提高的反应速率。总的来说,这项工作为制备高性能光催化剂的 TiO(2)-碳复合材料提供了新的思路,并有助于将其应用于环境保护问题。

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