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约旦鸡蛋、鸡肉和肉类中的有机氯农药残留情况。

Occurrence of organochlorine pesticide residues in eggs, chicken and meat in Jordan.

机构信息

Industrial Chemistry Centre, Royal Scientific Society, P.O. Box 1438, Al-Jubaiha, Amman 11941, Jordan.

出版信息

Chemosphere. 2010 Feb;78(6):667-71. doi: 10.1016/j.chemosphere.2009.12.012. Epub 2009 Dec 29.

Abstract

Organochlorine pesticide (OCP) residues in 519 samples; comprising eggs, chicken and meat (lamb and beef), collected from Jordan were determined. All samples were analyzed for their residual contents of aldrin, dichlorodiphenyltrichloroethane and metabolites (DDTs), dieldrin, endosulfan isomers, endrin, hexachlorocyclohexane isomers (HCHs), heptachlor, heptachlor epoxide and hexachlorobenzene (HCB). The samples were Soxhlet extracted for 8h in 250mL petroleum ether. The cleanup of the samples was performed by Florisil column chromatography and analysis was done on a gas chromatography equipped with an electron capture detector (GC-ECD). The results indicated that 28% (38/134), 20% (23/115) and 49% (131/270) of the examined eggs, chicken and meat samples, respectively, were contaminated with OCP residues. HCHs and DDTs are the most prominently noticed compounds, as they were detected at a high incidence. On the other hand, heptachlor, heptachlor epoxide, HCB, aldrin and endrin compounds were only present in less than 7% of the analyzed samples. These residues are present despite complete ban on the use of OCPs for agricultural purposes in Jordan. No residues of op'-DDD, op'-DDT, dieldrin, alpha-endosulfan and beta-endosulfan were detected.

摘要

对从约旦收集的 519 个样本(包括鸡蛋、鸡肉和肉类(羊肉和牛肉))中的有机氯农药 (OCP) 残留进行了测定。对所有样本进行了残留量分析,包括艾氏剂、滴滴涕和代谢物(DDTs)、狄氏剂、硫丹异构体、异狄氏剂、六氯环己烷异构体 (HCHs)、七氯、七氯环氧化物和六氯苯 (HCB)。样品用索氏提取器在 250mL 石油醚中提取 8 小时。通过 Florisil 柱层析对样品进行净化,并用配备电子捕获检测器 (GC-ECD) 的气相色谱仪进行分析。结果表明,在所检查的鸡蛋、鸡肉和肉类样本中,分别有 28%(38/134)、20%(23/115)和 49%(131/270)受到 OCP 残留的污染。HCHs 和 DDTs 是最显著的注意化合物,因为它们的检出率很高。另一方面,七氯、七氯环氧化物、HCB、艾氏剂和异狄氏剂化合物仅存在于不到 7%的分析样本中。尽管约旦已全面禁止 OCP 用于农业用途,但这些残留物仍存在。未检出 op'-DDD、op'-DDT、狄氏剂、α-硫丹和β-硫丹的残留。

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