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门多萨省(阿根廷)马尔贝克葡萄酒的酚类特征。

Phenolic characterization of malbec wines from mendoza province (Argentina).

机构信息

Laboratorio de Aromas y Sustancias Naturales, Estacíon Experimental Agropecuaria Mendoza, Instituto Nacional de Tecnologia Agropecuaria, San Martín 3853, 5507 Lujan de Cuyo, Mendoza, Argentina.

出版信息

J Agric Food Chem. 2010 Feb 24;58(4):2388-97. doi: 10.1021/jf903690v.

Abstract

Malbec is a wine grape variety that is now mainly produced in Mendoza and considered to be the emblematic cultivar of Argentina. Forty-four phenolic compounds, including hydroxybenzoic and hydroxycinnamic acids and different flavonoids, were identified and quantified in 61 monovarietal Malbec wines from 11 geographical zones of Mendoza province, using a reversed phase high-performance liquid chromatography system coupled to a diode array detector (HPLC-DAD). Among non-flavonoids, gallic, cis-caftaric, trans-coutaric, and caffeic acids presented the higher concentrations in all of the samples, whereas trans-resveratrol glucoside was present at concentrations from 0.6 to 1.3 mg/L. For the flavonoids, (+)-catechin and (-)-epicatechin presented the higher concentrations among flavan-3-ols with a ratio (+)-catechin/(-)-epicatechin from 1.3 to 2.1. An astilbin derivative and quercetin presented the higher concentrations for flavonols, whereas malvidin-3-glucoside and its derivatives were the major anthocyanins. For the first time the phenolic composition of Malbec wines from Mendoza province has been characterized.

摘要

马尔贝克(Malbec)是一种酿酒葡萄品种,如今主要在门多萨(Mendoza)产区生产,被认为是阿根廷的标志性葡萄品种。利用反相高效液相色谱系统结合二极管阵列检测器(HPLC-DAD),对门多萨省 11 个地理区域的 61 款单一马尔贝克葡萄酒进行分析,共鉴定和定量了 44 种酚类化合物,包括羟基苯甲酸和羟基肉桂酸以及不同的类黄酮。在所分析的所有样本中,没食子酸、顺式咖啡酸、反式柯因酸和咖啡酸的浓度最高,而反式白藜芦醇葡萄糖苷的浓度为 0.6 至 1.3mg/L。对于类黄酮,黄烷-3-醇中(+)-儿茶素和(-)-表儿茶素的浓度最高,(+)-儿茶素/(-)-表儿茶素的比例为 1.3 至 2.1。杨梅素衍生物和槲皮素的浓度最高,而矢车菊素-3-葡萄糖苷及其衍生物是主要的花色苷。这是首次对门多萨省马尔贝克葡萄酒的酚类成分进行了特征描述。

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