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Trityl-nitroxide biradicals as unique molecular probes for the simultaneous measurement of redox status and oxygenation.
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Synthesis of trityl radical-conjugated disulfide biradicals for measurement of thiol concentration.
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Designing Molecular Probes To Prolong Intracellular Retention: Application to Nitroxide Spin Probes.
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Effect of Solution Ionic Strength on the pK of the Nitroxide pH EPR Probe 2,2,3,4,5,5-Hexamethylimidazolidin-1-oxyl.
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Synthesis and properties of novel porphyrin spin probes containing isoindoline nitroxides.
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Three-dimensional electron paramagnetic resonance imaging of mice using ascorbic acid sensitive nitroxide imaging probes.
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Highly bioresistant, hydrophilic and rigidly linked trityl-nitroxide biradicals for cellular high-field dynamic nuclear polarization.
Chem Sci. 2022 Nov 17;13(47):14157-14164. doi: 10.1039/d2sc04668g. eCollection 2022 Dec 7.
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Synthesis and characterization of a Cu(ii) coordination-containing TAM radical as a nitroxyl probe.
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A C-Labeled Triarylmethyl Radical as an EPR Spin Probe Highly Sensitive to Molecular Tumbling.
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Synthesis of hydroxyethyl tetrathiatriarylmethyl radicals OX063 and OX071.
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Efficient cross-effect dynamic nuclear polarization without depolarization in high-resolution MAS NMR.
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1
Trityl-based EPR probe with enhanced sensitivity to oxygen.
Free Radic Biol Med. 2009 Sep 1;47(5):654-8. doi: 10.1016/j.freeradbiomed.2009.06.007. Epub 2009 Jun 10.
2
Synthesis of a BDPA-TEMPO biradical.
Org Lett. 2009 May 7;11(9):1871-4. doi: 10.1021/ol9001575.
3
Esterified trityl radicals as intracellular oxygen probes.
Free Radic Biol Med. 2009 Apr 1;46(7):876-83. doi: 10.1016/j.freeradbiomed.2008.12.011. Epub 2008 Dec 24.
4
Highly stable dendritic trityl radicals as oxygen and pH probe.
Chem Commun (Camb). 2008 Sep 28(36):4336-8. doi: 10.1039/b807406b. Epub 2008 Aug 15.
5
In vivo EPR measurement of glutathione in tumor-bearing mice using improved disulfide biradical probe.
Free Radic Biol Med. 2008 Aug 1;45(3):312-20. doi: 10.1016/j.freeradbiomed.2008.04.019. Epub 2008 Apr 23.
6
Synthesis and characterization of ester-derivatized tetrathiatriarylmethyl radicals as intracellular oxygen probes.
J Org Chem. 2008 Feb 15;73(4):1490-7. doi: 10.1021/jo7022747. Epub 2008 Jan 18.
7
Use of electron paramagnetic resonance spectroscopy to evaluate the redox state in vivo.
Antioxid Redox Signal. 2007 Oct;9(10):1757-71. doi: 10.1089/ars.2007.1718.
9
TOTAPOL: a biradical polarizing agent for dynamic nuclear polarization experiments in aqueous media.
J Am Chem Soc. 2006 Sep 6;128(35):11385-90. doi: 10.1021/ja061284b.
10
Simultaneous molecular imaging of redox reactions monitored by Overhauser-enhanced MRI with 14N- and 15N-labeled nitroxyl radicals.
Proc Natl Acad Sci U S A. 2006 Jan 31;103(5):1463-8. doi: 10.1073/pnas.0510670103. Epub 2006 Jan 23.

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