（S）-叔丁基PHOX（恶唑，4-（1,1-二甲基乙基）-2-[2-（二苯基膦基）苯基]-4,5-二氢-（4S）-）的制备 - Suppr

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PREPARATION OF (S)-tert-ButylPHOX (Oxazole, 4-(1,1-dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro- (4S)-).

作者信息

Krout Michael R, Mohr Justin T, Stoltz Brian M

出版信息

Organic Synth. 2009 Jan 1;86:181. doi: 10.15227/orgsyn.086.0181.

DOI:10.15227/orgsyn.086.0181

PMID:20072718

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2805096/

Abstract

摘要

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Catalytic enantioselective decarboxylative protonation.

J Am Chem Soc. 2006 Sep 6;128(35):11348-9. doi: 10.1021/ja063335a.

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