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金(III)催化的酮与酚的串联反应:高效高选择性合成官能化 4H-色烯。

Gold(III)-catalyzed tandem reaction of ketones with phenols: efficient and highly selective synthesis of functionalized 4H-chromenes.

机构信息

State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, People's Repubilc of China.

出版信息

J Org Chem. 2010 Feb 19;75(4):1309-12. doi: 10.1021/jo902619x.

DOI:10.1021/jo902619x
PMID:20073526
Abstract

An efficient and highly selective approach for the synthesis of functionalized 4H-chromenes has been developed via gold(III)-catalyzed condensation/annulation tandem reaction of ketones with phenols.

摘要

一种高效且高选择性的方法,通过金(III)催化的酮与苯酚的缩合/环化串联反应,已经被开发出来用于合成官能化的 4H-色烯。

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引用本文的文献

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Enantioselective one-pot synthesis of 4-chromene derivatives catalyzed by a chiral Ni(ii) complex.手性镍(II)配合物催化对映选择性一锅法合成4-色烯衍生物
RSC Adv. 2020 Dec 16;10(72):44437-44441. doi: 10.1039/d0ra08906k. eCollection 2020 Dec 9.
2
1,3-Bis(4-chloro-phen-yl)-1-methyl-1H-benzo[f]chromene.1,3-双(4-氯苯基)-1-甲基-1H-苯并[f]色烯
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 23;66(Pt 7):o1760. doi: 10.1107/S1600536810022610.