Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China.
Chem Commun (Camb). 2010 Feb 7;46(5):755-7. doi: 10.1039/b919895d. Epub 2009 Nov 27.
Nanosized anatase TiO(2) single crystals with 18% {001} facets have a raised conduction band minimum by 0.1 eV, and exhibit photocatalytic activity both for generating *OH radicals and for splitting water into hydrogen that is markedly superior--by factors of 5.6 and 8.2, respectively--to reference ca. 3 microm anatase TiO(2) with 72% {001} facets.
具有 18%{001}面的纳米级锐钛矿 TiO(2)单晶使导带底升高了 0.1eV,并表现出明显优于参考约 3μm 锐钛矿 TiO(2)(72%{001}面)的光催化活性,分别提高了 5.6 倍和 8.2 倍,用于生成*OH 自由基和将水分解为氢气。