双(咪唑啉-2-硫酮)铜(I)催化的炔烃区域选择性硼加成反应。
Bis(imidazoline-2-thione)-copper(I) catalyzed regioselective boron addition to internal alkynes.
机构信息
Department of Chemistry, Sungkyunkwan University, Suwon 440-746, Korea.
出版信息
Chem Commun (Camb). 2010 Feb 7;46(5):758-60. doi: 10.1039/b919515g. Epub 2009 Nov 30.
DOI:10.1039/b919515g
PMID:20087511
Abstract
New catalytic systems based on a bis(1,3-disubstituted imidazoline 2-thione)-copper complex have been developed for the highly regioselective boration of internal alkynes.
摘要
已开发出基于双（1,3-二取代咪唑啉 2-硫酮）-铜配合物的新型催化体系，用于高度区域选择性的内炔硼化反应。
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