Department of Chemistry, National Cheng Kung University, No. 1 Ta-Hsueh Road, 70101 Tainan, Taiwan.
Org Lett. 2011 Sep 16;13(18):4794-7. doi: 10.1021/ol201814q. Epub 2011 Aug 15.
In the presence of a catalytic system comprised of NiBr(2)(dppe) and Zn, arylacetylenes undergo tetramerization to form linear octatetraenes, generally in good to excellent yields. The structure of the coupling products was verified by X-ray crystallography.
在由 NiBr(2)(dppe)和 Zn 组成的催化体系存在下，芳基乙炔发生三聚反应形成线性八聚三烯，通常产率良好到优秀。通过 X 射线晶体学验证了偶联产物的结构。
