介孔硅负载的复分解催化剂：在环流反应器中的应用。
Mesoporous silica-supported catalysts for metathesis: application to a circulating flow reactor.
机构信息
Institute of Bioengineering and Nanotechnology, 31 Biopolis Way, 138669, The Nanos, Singapore.
出版信息
Chem Commun (Camb). 2010 Feb 7;46(5):806-8. doi: 10.1039/b917986k. Epub 2009 Nov 30.
DOI:10.1039/b917986k
PMID:20087527
Abstract
Using click chemistry for linkage, a ruthenium-based metathesis catalyst was efficiently immobilized on nanoporous silica. The heterogenized catalyst exhibited good activity and recyclability for various substrates. An interesting application was demonstrated for a continuous process using a circulating flow reactor.
摘要
利用点击化学进行键合，将基于钌的复分解催化剂有效地固定在纳米孔硅上。负载化催化剂对各种底物表现出良好的活性和可回收性。通过使用循环流动反应器，展示了一种有趣的连续工艺应用。
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