Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan.
Org Biomol Chem. 2010 Feb 7;8(3):511-21. doi: 10.1039/b920434b. Epub 2009 Dec 14.
Herein, we describe Hg(OTf)(2) as a new catalytic system for organic synthesis, which can achieve the hydration of alkynes, C-C bond forming cyclizations, heterocycle synthesis and cyclization initiated by allylic alcohols at very high catalytic turnovers under mild conditions. The first solid-supported mercuric salt, silaphenylmercuric triflate, was also developed and found to act as a powerful catalyst for most Hg(OTf)(2)-catalyzed reactions.
在这里，我们描述了 Hg(OTf)(2)作为一种新的有机合成催化体系，它可以在温和条件下以非常高的催化转化率实现炔烃的水合、C-C 键形成环化、杂环合成和烯丙醇引发的环化。还开发了第一个固载的汞盐，即 silaphenylmercuric 三氟甲磺酸酯，并发现它可以作为大多数 Hg(OTf)(2)催化反应的有力催化剂。
