“连接”钌（II）芳基酮还原催化剂的动力学和结构研究。
Kinetic and structural studies on 'tethered' Ru(II) arene ketone reduction catalysts.
机构信息
Asymmetric Catalysis Group, Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.
出版信息
Dalton Trans. 2010 Feb 7;39(5):1395-402. doi: 10.1039/b915932k. Epub 2009 Dec 1.
DOI:10.1039/b915932k
PMID:20104368
Abstract
A series of kinetic and structural investigations on ruthenium-based catalysts for asymmetric transfer hydrogenation (ATH) of ketones are reported. A method is reported for monitoring the formation of ruthenium hydride species in real time using (1)H NMR spectroscopy.
摘要
报道了一系列用于酮的不对称转移氢化（ATH）的钌基催化剂的动力学和结构研究。本文报道了一种使用 (1)H NMR 光谱实时监测钌氢化物物种形成的方法。
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