手性半夹心配合物不对称氢化的实用方面和机理。
Practical aspects and mechanism of asymmetric hydrogenation with chiral half-sandwich complexes.
机构信息
Department of Organic Technology, Institute of Chemical Technology, Technická 5, CZ-166 28 Prague, Czech Republic.
出版信息
Molecules. 2013 Jun 10;18(6):6804-28. doi: 10.3390/molecules18066804.
Abstract
This review is oriented toward the asymmetric transfer hydrogenation (ATH) of imines regarding mostly fundamental, yet important topics from the practical point of view. Development of analytical methods for the monitoring of ATH (i.e., kinetics and stereoselectivity) belongs to those topics, as well as studies on the influence of reaction conditions and structural variations on the reaction performance. The second part is devoted to the reaction mechanism with the emphasis on imine ATH and catalyst behaviour under acidic conditions. The review also addresses the asymmetric hydrogenation (AH) of ketones and imines using molecular hydrogen and the application of ATH in pharmaceutical projects. The contributions of our group to each area are included.
摘要
这篇综述主要针对亚胺的不对称转移氢化（ATH），从基础但重要的角度探讨了这一主题，同时也涉及了从实用角度出发的分析方法的发展，例如ATH 的监测（即动力学和立体选择性）以及对反应条件和结构变化对反应性能影响的研究。第二部分致力于反应机制，重点讨论了在酸性条件下亚胺 ATH 和催化剂的行为。综述还涉及了酮和亚胺的不对称氢化（AH）使用分子氢以及 ATH 在药物项目中的应用。本综述中还包括了我们小组在各个领域的贡献。
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