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量子点和纳米复合材料。

Quantum dots and nanocomposites.

机构信息

Department of Metallurgical and Materials Engineering, School of Engineering, Federal University of Minas Gerais, 31270, 901, Belo Horizonte, Minas Gerais, Brazil.

出版信息

Wiley Interdiscip Rev Nanomed Nanobiotechnol. 2010 Mar-Apr;2(2):113-29. doi: 10.1002/wnan.78.

Abstract

Quantum dots (QDs), also known as semiconducting nanoparticles, are promising zero-dimensional advanced materials because of their nanoscale size and because they can be engineered to suit particular applications such as nonlinear optical devices (NLO), electro-optical devices, and computing applications. QDs can be joined to polymers in order to produce nanocomposites which can be considered a scientific revolution of the 21st century. One of the fastest moving and most exciting interfaces of nanotechnology is the use of QDs in medicine, cell and molecular biology. Recent advances in nanomaterials have produced a new class of markers and probes by conjugating semiconductor QDs with biomolecules that have affinities for binding with selected biological structures. The nanoscale of QDs ensures that they do not scatter light at visible or longer wavelengths, which is important in order to minimize optical losses in practical applications. Moreover, at this scale, quantum confinement and surface effects become very important and therefore manipulation of the dot diameter or modification of its surface allows the properties of the dot to be controlled. Quantum confinement affects the absorption and emission of photons from the dot. Thus, the absorption edge of a material can be tuned by control of the particle size. This paper reviews developments in the myriad of possibilities for the use of semiconductor QDs associated with molecules producing novel hybrid nanocomposite systems for nanomedicine and bioengineering applications.

摘要

量子点(QDs),也称为半导体纳米粒子,是有前途的零维先进材料,因为它们的纳米尺寸以及可以根据特定应用进行工程设计,例如非线性光学器件(NLO)、电光器件和计算应用。QDs 可以与聚合物结合以产生纳米复合材料,这可以被认为是 21 世纪的科学革命。纳米技术中发展最快、最令人兴奋的界面之一是将 QDs 用于医学、细胞和分子生物学。纳米材料的最新进展通过将半导体 QDs 与对与选定生物结构结合具有亲和力的生物分子缀合,产生了一类新的标记物和探针。QDs 的纳米尺寸确保它们不会在可见光或更长波长处散射光,这对于最小化实际应用中的光损耗非常重要。此外,在这个尺度上,量子限制和表面效应变得非常重要,因此对点直径的操纵或其表面的修饰可以控制点的性质。量子限制会影响从点发出的光子的吸收和发射。因此,可以通过控制颗粒尺寸来调整材料的吸收边缘。本文综述了与分子相关的半导体 QDs 的多种可能用途的发展情况,这些分子产生了用于纳米医学和生物工程应用的新型混合纳米复合材料系统。

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