无配体铜（I）催化的唑类分子内直接 C-H 官能化反应。
Ligand-free copper(I)-catalysed intramolecular direct C-H functionalization of azoles.
机构信息
Kimika Organikoa II Saila, Zientzia eta Teknologia Fakultatea, Euskal Herriko Unibertsitatea, PO Box 644, 48080, Bilbao, Spain.
出版信息
Org Biomol Chem. 2010 Feb 21;8(4):841-5. doi: 10.1039/b916549e. Epub 2009 Dec 23.
DOI:10.1039/b916549e
PMID:20135042
Abstract
The first examples of copper-catalysed intramolecular direct C-arylation of azaheterocycles for the synthesis of complex heterofused compounds is presented, featuring an unprecedented arylation via C-H activation of 9H-purine and 4-azabenzimidazole.
摘要
首次提出了铜催化的氮杂环芳烃分子内直接 C-芳基化反应，用于合成复杂杂环化合物，通过 9H-嘌呤和 4-氮杂苯并咪唑的 C-H 活化，实现了前所未有的芳基化。
Zotero 插件