CEFT, Departamento de Engenharia Química, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Robert Frias, 4200-465 Porto, Portugal.
J Colloid Interface Sci. 2010 Apr 15;344(2):513-20. doi: 10.1016/j.jcis.2010.01.025. Epub 2010 Jan 25.
The electro-osmotic flow of a viscoelastic fluid between parallel plates is investigated analytically. The rheology of the fluid is described by the Phan-Thien-Tanner model. This model uses the Gordon-Schowalter convected derivative, which leads to a non-zero second normal stress difference in pure shear flow. A nonlinear Poisson-Boltzmann equation governing the electrical double-layer field and a body force generated by the applied electrical potential field are included in the analysis. Results are presented for the velocity and stress component profiles in the microchannel for different parametric values that characterize this flow. Equations for the critical shear rates and maximum electrical potential that can be applied to maintain a steady fully developed flow are derived and discussed.
本文对平行板间黏弹性流体的电渗流动进行了分析。该流体的流变学特性由 Phan-Thien-Tanner 模型描述。该模型采用 Gordon-Schowalter 共轭导数,导致纯剪切流中出现非零的第二法向应力差。分析中包括控制电双层场的非线性泊松-玻尔兹曼方程和由外加电场产生的体力。给出了不同参数值下微通道中速度和应力分量分布的结果。推导出并讨论了可以应用于维持稳定完全发展流动的临界剪切速率和最大电势的方程。