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单分散、尺寸可调的 SnS 纳米粒子的简便合成,有望用于太阳能电池能量转换。

Facile synthesis of monodisperse, size-tunable SnS nanoparticles potentially for solar cell energy conversion.

机构信息

College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People's Republic of China.

出版信息

Nanotechnology. 2010 Mar 12;21(10):105707. doi: 10.1088/0957-4484/21/10/105707. Epub 2010 Feb 16.

Abstract

A simple strategy to synthesize monodisperse, single-crystalline and size-tunable SnS nanoparticles was reported. An active sulfur precursor bis(trimethylsilyl)sulfide was applied to enable fast nucleation of tin species in oleylamine. As-synthesized nanoparticles were easily dispersed in a non-polar organic solvent and formed a uniform solution which showed complete absorption of visible light. The smooth, dense-packed and crack-free SnS film was achieved by spin-coating that showed an enhanced photoresponse via methanol treatment. Owing to their noble merits, as-synthesized SnS nanoparticles could be a potential nanomaterial for solar cell application.

摘要

本文报道了一种简单的策略,用于合成单分散、单晶和尺寸可调的 SnS 纳米粒子。使用活性硫前体双(三甲基硅基)硫来实现锡物种在油胺中的快速成核。所合成的纳米粒子容易分散在非极性有机溶剂中,并形成均匀的溶液,完全吸收可见光。通过旋涂法可以得到光滑、致密且无裂纹的 SnS 薄膜,通过甲醇处理可以提高其光电响应性能。由于其优异的性能,所合成的 SnS 纳米粒子可能成为太阳能电池应用的一种潜在纳米材料。

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