Pd(OCOCF3)2/NPMoV/O2 体系催化简单烯烃与二苯胺的分子间有氧氧化烯丙基胺化反应。
Intermolecular aerobic oxidative allylic amination of simple alkenes with diarylamines catalyzed by the Pd(OCOCF3)2/NPMoV/O2 system.
机构信息
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, High Technology Research Center, and ORDIST, Kansai University, Suita, Osaka 564-8680, Japan.
出版信息
Org Lett. 2010 Mar 19;12(6):1372-4. doi: 10.1021/ol100292g.
PMID:20158264
Abstract
Intermolecular aerobic oxidative allylic amination of simple alkyl alkenes with simple amines such as diphenylamine was induced by a Pd(OCOCF(3))(2)/NPMoV catalytic system, leading to the corresponding (E)-allylamines in good yield and selectivity through the formation of (eta(3)-allyl)palladium(II) trifluoroacetate species as a possible key intermediate.
摘要
在 Pd(OCOCF3)2/NPMoV 催化体系的诱导下，简单烷基烯烃与简单胺（如二苯胺）发生分子间有氧氧化烯丙基胺化反应，通过形成（η3-烯丙基）钯（II）三氟乙酸盐作为可能的关键中间体，以良好的收率和选择性得到相应的（E）-烯丙胺。
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