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本文引用的文献

1
Reactions of nitroso hetero-Diels-Alder cycloadducts with azides: stereoselective formation of triazolines and aziridines.亚硝基杂环狄尔斯-阿尔德环加成物与叠氮化物的反应：三唑啉和氮丙啶的立体选择性形成
J Org Chem. 2007 May 11;72(10):3929-32. doi: 10.1021/jo0701987. Epub 2007 Apr 13.
2
Stereoselective total synthesis of (+)-streptazolin by using a temporary silicon-tethered RCM strategy.采用临时硅连接的RCM策略对(+)-链唑啉进行立体选择性全合成。
J Org Chem. 2006 Jul 7;71(14):5221-7. doi: 10.1021/jo060555y.
3
Synthetic application of acylnitroso Diels-Alder derived aminocyclopentenols: total synthesis of (+)-streptazolin.酰基亚硝基环戊二烯加成反应衍生的氨基环戊烯醇的合成应用：（+）-链唑啉的全合成
J Org Chem. 2004 Dec 10;69(25):8836-41. doi: 10.1021/jo048606j.
4
Chemoenzymatic synthesis and synthetic application of enantiopure aminocyclopentenols: total synthesis of carbocyclic (+)-uracil polyoxin C and its alpha-epimer.对映体纯氨基环戊烯醇的化学酶法合成及其合成应用：碳环（+）-尿嘧啶多氧霉素C及其α-差向异构体的全合成
J Org Chem. 2004 Jun 25;69(13):4538-40. doi: 10.1021/jo0496796.
5
Regio- and stereoselective ring openings of 3-Aza-2-oxabicyclo[2.2.1]hept-5-ene systems with copper catalyst-modified grignard reagents: application to the synthesis of an inhibitor of 5-lipoxygenase.铜催化剂改性格氏试剂对3-氮杂-2-氧杂双环[2.2.1]庚-5-烯体系的区域和立体选择性开环反应：在5-脂氧合酶抑制剂合成中的应用
J Org Chem. 2002 Jun 14;67(12):4115-21. doi: 10.1021/jo016275u.
6
Novel 1,4-benzodiazepines from acylnitroso-derived hetero-Diels-Alder cycloadducts.
Org Lett. 2002 Jan 10;4(1):139-41. doi: 10.1021/ol017036w.
7
The Hetero Diels-Alder Reactions between D-Mannose-Derived Halonitroso Compounds and Cyclopentadiene: Scope and Limitations.
J Org Chem. 1998 Feb 6;63(3):885-888. doi: 10.1021/jo971696q.
8
Regio- and stereochemically controlled formation of hydroxamic acid containing anti- or syn-1,4-cycloalkenols from acylnitroso-derived Diels-Alder adducts.通过酰基亚硝基衍生的狄尔斯-阿尔德加合物区域和立体化学控制地形成含异羟肟酸的反式或顺式-1,4-环烯醇。
J Org Chem. 2001 Apr 6;66(7):2466-9. doi: 10.1021/jo010094a.

布伦斯特德酸介导的亚硝基环加合物在无水条件下的开环反应。

Brønsted acid-mediated opening of nitroso cycloadducts under anhydrous conditions.

作者信息

Bodnar Brian S, Miller Marvin J

机构信息

Deparment of Chemistry and Biochemistry, 251 Nieuwland Science Hall, University of Notre Dame, Notre Dame, IN 46556.

出版信息

Tetrahedron Lett. 2009 Feb 18;50(7):796-798. doi: 10.1016/j.tetlet.2008.11.120.

DOI:10.1016/j.tetlet.2008.11.120
PMID:20160837
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2613285/
Abstract

An unusual bicyclic hydroxamate resulted from C-O bond cleavage of acylnitroso hetero-Diels-Alder cycloadducts when treated with catalytic Brønsted acids under anhydrous conditions. Similarly, the formation of a nitrone was observed using one equivalent of triflic acid.

摘要

在无水条件下用催化布朗斯特酸处理时，酰基亚硝基杂狄尔斯-阿尔德环加成物的C-O键断裂产生了一种不寻常的双环异羟肟酸酯。类似地，使用一当量的三氟甲磺酸时观察到硝酮的形成。