AgOAc/TF-BiphamPhos 催化的亚胺叶立德与丙二烯马来酸盐的 exo-选择性不对称 1,3-偶极环加成反应。
exo-Selective asymmetric 1,3-dipolar cycloaddition of azomethine ylides with alkylidene malonates catalyzed by AgOAc/TF-BiphamPhos.
机构信息
College of Chemistry and Molecular Sciences, Wuhan University, 430072, China.
出版信息
Chem Commun (Camb). 2010 Mar 14;46(10):1727-9. doi: 10.1039/b919625k. Epub 2010 Feb 5.
DOI:10.1039/b919625k
PMID:20177630
Abstract
The first exo-selective asymmetric 1,3-dipolar cycloaddition of alkylidene malonates with azomethine ylides catalyzed by AgOAc/TF-BiphamPhos has been reported in good yields and good to excellent enantio-/diastereoselectivities.
摘要
首次报道了在 AgOAc/TF-BiphamPhos 催化下，亚甲基丙二酸酯与亚胺叶立德的外消旋 1,3-偶极环加成反应，产率高，对映选择性和非对映选择性好至优秀。
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