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金属催化不对称转化中的氟：最轻的卤素却产生巨大影响。

Fluorine in metal-catalyzed asymmetric transformations: the lightest halogen causing a massive effect.

作者信息

Lauzon Samuel, Ollevier Thierry

机构信息

Département de Chimie, Université Laval 1045 Avenue de la Médecine Québec QC G1V 0A6 Canada

出版信息

Chem Sci. 2022 Aug 8;13(37):10985-11008. doi: 10.1039/d2sc01096h. eCollection 2022 Sep 28.

DOI:10.1039/d2sc01096h
PMID:36320478
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9516955/
Abstract

This review aims at providing an overview of the most significant applications of fluorine-containing ligands reported in the literature starting from 2001 until mid-2021. The ligands are classified according to the nature of the donor atoms involved. This review highlights both metal-ligand interactions and the structure-reactivity relationships resulting from the presence of the fluorine atom or fluorine-containing substituents on chiral catalysts.

摘要

本综述旨在概述2001年至2021年年中期间文献报道的含氟配体的最重要应用。这些配体根据所涉及的供体原子的性质进行分类。本综述重点介绍了金属-配体相互作用以及手性催化剂上氟原子或含氟取代基的存在所导致的结构-反应性关系。

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9
Enantioselective palladium/copper-catalyzed C-C σ-bond activation synergized with Sonogashira-type C(sp)-C(sp) cross-coupling alkynylation.对映选择性钯/铜催化的C-C σ键活化与Sonogashira型C(sp)-C(sp)交叉偶联炔基化协同作用。
Chem Sci. 2019 Jun 21;10(32):7579-7583. doi: 10.1039/c9sc02431j. eCollection 2019 Aug 28.
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The Role of Trichloroacetimidate To Enable Iridium-Catalyzed Regio- and Enantioselective Allylic Fluorination: A Combined Experimental and Computational Study.三氯乙腈基作为铱催化区域和对映选择性烯丙基氟化反应的助剂的作用：实验与计算的综合研究。
J Am Chem Soc. 2019 Sep 18;141(37):14843-14852. doi: 10.1021/jacs.9b07575. Epub 2019 Sep 9.