Industry Department, Natural and Exact Sciences School, Buenos Aires University, Ciudad Universitaria, Buenos Aires, Argentina.
J Agric Food Chem. 2010 Mar 24;58(6):3793-800. doi: 10.1021/jf903844b.
Chemical and rheological characteristics of fractions enriched in soluble dietary fiber are reported. These fractions were obtained through acid hydrolysis of butternut (Cucurbita moschata Duch ex Poiret) and red beet (Beta vulgaris L. var. conditiva) cell wall enriched powders. Hydrolysis was performed using citric acid at different pH values and reaction times (2 and 3 h). Yields obtained for butternut fractions were between 21 and 28 g/100 g; for red beet, yields were 24 and 31 g/100 g for pH 1.5 and 11 and 17 g/100 g for pH 2.0 for previously mentioned times; in general, the increase of the yield was directly correlated with the decrease of pH and the increase of reaction time. Products enriched in low methoxyl pectins were obtained in all cases. At the lowest pH assayed, pectins were essentially constituted by homogalacturonan; a significant content of neutral sugars was determined at the higher extraction pH. Neutral sugars were constituted mainly by arabinose, galactose, rhamnose, and glucose in different proportions for each fraction; in general, butternut fractions showed high glucose contents. Flow behavior for 2.00% (w/v) aqueous systems of the different products was evaluated. Data obtained for fractions isolated at pH 1.5 fit to Herschel-Bulkley and Cross models while those isolated at pH 2.0 fit to Ostwald and Cross models. All samples showed low viscosity and, hence, poor thickening properties.
报告了富含可溶性膳食纤维的级分的化学和流变学特性。这些级分是通过对富含细胞壁的胡桃南瓜(Cucurbita moschata Duch ex Poiret)和红甜菜(Beta vulgaris L. var. conditiva)粉末进行酸水解获得的。水解使用柠檬酸在不同的 pH 值和反应时间(2 和 3 小时)下进行。胡桃南瓜级分的产率在 21 至 28 g/100 g 之间;对于红甜菜,pH 值为 1.5 和 11 时的产率为 24 和 31 g/100 g,pH 值为 2.0 时的产率为 17 g/100 g,对于上述时间;一般来说,产率的增加与 pH 值的降低和反应时间的增加直接相关。在所有情况下都获得了富含低甲氧基果胶的产物。在测定的最低 pH 值下,果胶基本上由同质半乳糖醛酸组成;在较高的提取 pH 值下测定到大量中性糖。中性糖主要由阿拉伯糖、半乳糖、鼠李糖和葡萄糖以不同比例构成;一般来说,胡桃南瓜级分的葡萄糖含量较高。评估了不同产物在 2.00%(w/v)水性体系中的流动行为。在 pH 值为 1.5 时分离的级分的数据适合 Herschel-Bulkley 和 Cross 模型,而在 pH 值为 2.0 时分离的级分适合 Ostwald 和 Cross 模型。所有样品的粘度均较低,因此增稠性能较差。