Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.
J Am Chem Soc. 2010 Mar 24;132(11):3648-9. doi: 10.1021/ja909522s.
A Pd(II)-catalyzed C-H activation/trifluoromethylation of arenes with an electrophilic trifluoromethylation reagent using diverse heterocycle directing groups is reported. The presence of trifluoroacetic acid is crucial for this catalytic reaction.
报道了一种使用不同杂环导向基团的 Pd(II)催化芳环的 C-H 活化/三氟甲基化反应，该反应使用亲电的三氟甲基化试剂。三氟乙酸的存在对这个催化反应至关重要。
