Zhou Hai-dong, Huang Xia, Wang Xiao-lin, Wen Xiang-hua
Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China.
Huan Jing Ke Xue. 2009 Dec;30(12):3590-5.
The recombinant yeast estrogen screen (YES) was used to evaluate the estrogenic activities of sewage samples from every step of three sewage treatment plants (STPs) in Beijing, China. Meanwhile, eight target endocrine-disrupting compounds (EDCs) in corresponding sewage samples were simultaneously analyzed by GC/MS system to further elucidate the variations of their estrogenic activities. The results indicated that estrogenic activities could be considerably reduced by STPs with the rate of 82.2%-97.0%. However,they were still detected in the effluent samples with the values of EEQs (expressed as E2 equivalents) 2.6-16.0 ng/L. In addition,STPs could not completely remove the target EDCs according to GC/MS analysis. The average concentration of 17alpha-E2 in the effluent was the lowest with the value of 13.5 ng/L, and the concentration of BPA (106.4 ng/L) was the largest. The estrogenic activities of effluent samples were mainly composed of steroid estrogens. Consequently, potential environmental risk can be caused by the discharge of effluents from STPs. How to effectively remove steroid estrogens during sewage treatment is, therefore, of a major concern.
采用重组酵母雌激素筛选法(YES)对中国北京三座污水处理厂(STPs)各处理阶段的污水样本的雌激素活性进行评估。同时,利用气相色谱/质谱联用系统(GC/MS)对相应污水样本中的八种目标内分泌干扰化合物(EDCs)进行同步分析,以进一步阐明其雌激素活性的变化情况。结果表明,污水处理厂可使雌激素活性大幅降低,去除率为82.2% - 97.0%。然而,在出水样本中仍可检测到雌激素活性,其以E2当量表示的雌激素等效量(EEQs)值为2.6 - 16.0 ng/L。此外,根据GC/MS分析,污水处理厂无法完全去除目标内分泌干扰化合物。出水中17α - E2的平均浓度最低,为13.5 ng/L,而双酚A(BPA)的浓度最高,为106.4 ng/L。出水样本的雌激素活性主要由类固醇雌激素构成。因此,污水处理厂的出水排放可能会造成潜在的环境风险。故而,如何在污水处理过程中有效去除类固醇雌激素成为一个主要关注点。