通过非血红素铁加氧酶 CloR 的功能模型对α-羟基酸进行氧化脱羧。
Oxidative decarboxylation of alpha-hydroxy acids by a functional model of the nonheme iron oxygenase, CloR.
机构信息
Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 2A&2B Raja S. C. Mullick Road, Jadavpur, Kolkata-700032, India.
出版信息
Chem Commun (Camb). 2010 Mar 21;46(11):1830-2. doi: 10.1039/b925389k. Epub 2010 Feb 12.
Abstract
Iron(II)-alpha-hydroxy acid complexes of a tripodal N4 ligand undergo oxidative decarboxylation upon exposure to O(2) and mimic the aliphatic C1-C2 cleavage step catalyzed by CloR.
摘要
三齿 N4 配体的铁(II)-α-羟基酸配合物在暴露于 O(2)时会发生氧化脱羧反应，模拟 CloR 催化的脂肪族 C1-C2 断裂步骤。
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