Kovacs G J, Scott G D
Appl Opt. 1978 Oct 15;17(20):3314-22. doi: 10.1364/AO.17.003314.
The attenuated total reflection (ATR) angular spectra of a layered system of Ag-MgF(2)-Ag, sandwiched between glass and air, have been measured at three different wavelengths in the visible region. Resonant electromagnetic (EM) oscillations are detected as narrow minima in the reflectance and sometimes as accompanying maxima in the transmittance of both p- and s-polarized light. Detailed calculations of the resonant EM fields illustrate the nature of the oscillations. Discrepancies between theory and experiment are thought to be due largely to the surface roughness of evaporated MgF(2) films. A cermet layer is imagined to form at the MgF(2)-Ag interface, and also an induced roughness layer at the Ag-air interface. When the optical constants of the cermet and roughness layers are evaluated by the Maxwell Garnett theory, the discrepancies for both polarizations can be accounted for in a consistent manner at all three wavelengths.
夹在玻璃和空气之间的Ag-MgF₂-Ag层状系统的衰减全反射(ATR)角谱已在可见光区域的三个不同波长下进行了测量。共振电磁(EM)振荡在反射率中被检测为窄的极小值,有时在p偏振光和s偏振光的透射率中表现为伴随的极大值。对共振电磁场的详细计算阐明了振荡的性质。理论与实验之间的差异被认为主要是由于蒸发的MgF₂薄膜的表面粗糙度。设想在MgF₂-Ag界面处形成金属陶瓷层,并且在Ag-空气界面处也形成诱导粗糙度层。当通过麦克斯韦-加尼特理论评估金属陶瓷层和粗糙度层的光学常数时,在所有三个波长下,两种偏振的差异都可以以一致的方式得到解释。