Department of Chemistry, Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK.
Chem Commun (Camb). 2010 Apr 7;46(13):2191-3. doi: 10.1039/b924899d. Epub 2010 Feb 25.
The discovery and development of an efficient ene carbocyclization of 1,3-dicarbonyl compounds bearing pendent terminal alkyne substituents under 3-nitrobenzeneboronic acid catalysis is described. The reaction is efficient, easy to perform and general to a wide range of ketoester substrates.
本文描述了在 3-硝基苯硼酸催化下，带有末端炔基取代基的 1,3-二羰基化合物的高效烯碳环化反应的发现和发展。该反应效率高、易于操作，并且对广泛的酮酯底物具有普遍性。
