Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario, Canada K1S 5B6.
Chem Asian J. 2010 May 3;5(5):1006-29. doi: 10.1002/asia.200900596.
This Focus Review describes the emerging class of near-infrared (NIR) organic compounds containing the conjugated polyene, polymethine, and donor-acceptor chromophores and exploration of their NIR-absorbing, NIR-fluorescence, and NIR-photosensitizing properties for potential applications in heat absorbers, solar cells, and NIR light-emitting diodes. Examples of NIR organic compounds are reviewed with emphasis on the molecular design, NIR absorption, and fluorescence and particular emerging applications. The donor-acceptor type of NIR chromophores are particularly introduced owing to some unique features, including the designer-made energy gaps, facile synthesis, good processability, and controllable morphology and properties in the solid state. Future directions in research and development of NIR organic materials and applications are then offered from a personal perspective.
这篇重点综述描述了新兴的近红外(NIR)有机化合物类别,其中包含共轭聚烯、聚甲川和给体-受体发色团,并探索了它们在潜在应用中的 NIR 吸收、NIR 荧光和 NIR 光致敏化特性,这些应用包括热吸收体、太阳能电池和 NIR 发光二极管。本文重点介绍了 NIR 有机化合物的分子设计、NIR 吸收和荧光以及特定的新兴应用。特别介绍了给体-受体型 NIR 发色团,因为它们具有一些独特的特点,包括可设计的能隙、易于合成、良好的加工性以及在固态中可控的形态和性能。然后,从个人角度提供了 NIR 有机材料的研究和开发以及应用的未来方向。