Kundu Subrata, Liang Hong
Materials Science and Mechanical Engineering, Texas A & M University, College Station, TX 77843-3123, USA.
J Nanosci Nanotechnol. 2010 Feb;10(2):746-54. doi: 10.1166/jnn.2010.1808.
In this report, we described the very fast synthesis of gold nanoprisms under microwave heating for 60-90 s in the presence of 2-naphthol (2-N) as a new reducing agent. The growth of the particles with different shapes (spherical, polygonal or triangular/prisms etc.) were found to be functions of the surfactant-to-metal-ion molar ratio and the concentration of 2-N. The evolved nanoprisms were approximately 110 +/- 10 nm in diameter and the particles size and shape was successfully tuned just by varying the molar ratio of the reactants. This process can be extended to the synthesis of other nonmaterial with desired sizes and shapes. The method we generated might find variety of application in many areas such as catalysis, clinical and diagnostic medicine, and nanoelectronics.
在本报告中,我们描述了在微波加热60 - 90秒的条件下,以2 - 萘酚(2 - N)作为一种新型还原剂快速合成金纳米棱柱的过程。发现具有不同形状(球形、多边形或三角形/棱柱形等)的颗粒生长是表面活性剂与金属离子摩尔比以及2 - N浓度的函数。所生成的纳米棱柱直径约为110±10纳米,并且仅通过改变反应物的摩尔比就能成功调节颗粒的大小和形状。该过程可以扩展到合成具有所需尺寸和形状的其他纳米材料。我们开发的这种方法可能在催化、临床和诊断医学以及纳米电子学等许多领域有多种应用。